Evaluation of the efficiency of chiral atropisomeric phosphine ligands in asymmetric processes catalyzed by transition metal salts Part 1: Evaluation of steric effects
Journal Title: CHEMIK nauka-technika-rynek - Year 2012, Vol 66, Issue 7
Abstract
Asymmetric synthesis with the use of chiral complexes of transition metals is one of the most economic and environment friendly organic transformations applied in the pharmaceutical industry. However, due to the lack of a universal theory that would bind catalyst structure with synthesis stereoselectivity, selecting an appropriate catalyst for a new reaction is still performed empirically. The aim of this review is to indicate relations between catalyst structure and its efficiency, which may in the future facilitate the selection of an optimum catalytic system.
Authors and Affiliations
Oleg Demchuk, Elżbieta Łastawiecka, Michał Pietrusiewicz
Keywords
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