Formation of Interatomic Bonds of the Fumed Synthesis of Composites SiO2+Al2O3
Journal Title: Фізика і хімія твердого тіла - Year 2015, Vol 16, Issue 2
Abstract
Crystalline and electronic structures of SiO2/Al2O3 mixtures have been analyzed using X-ray diffraction (XRD) and ultra-soft X-ray emission spectroscopy (USXES). Comparison of ultrasoft X-ray emission AlLα-, SiLα- and OKα-bands redistribution Alsp-, Sisp- and Op-valence electrons when changing the mass ratio (0,23Al2O3+0,77 SiO2;, 0,30Al2O3+0,70SiO2; 0,75Al2O3+25 SiO2) and depending on the method of obtaining them. Expansion OKα-emission bands showed an increase in population of Opπ-levels of oxygen in the formation of pyrogenic composites with different contents of aluminum oxide and silicon dioxide. Analysis AlLα-, SiLα- emission bands allowed to explain the increase of population Opπ-levels of oxygen and present the morphology formation of particles different of pyrogenic composites during synthesis.
Authors and Affiliations
Ya. V. Zaulychnyy, V. Ya. lkiv, Y. V. Yavorskyi, V. М. Gun'ko, V. I. Zarko, М. V. Karpetz
Keywords
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- EP ID EP308003
- DOI 10.15330/pcss.16.2.425-431
- Views 51
- Downloads 0
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