One-pot, clean and energy efficient synthesis of dibenzo[b,f][1,4]oxazepine derivatives promoted by ultrasound
Journal Title: Asian Journal of Green Chemistry - Year 2018, Vol 2, Issue 1
Abstract
In the present study, a variety of dibenzo [b,f][1,4] oxazepine derivatives was successfully synthesized in good yields under ultrasonic irradiation as an environmental friendly technique. This one-pot method is practically reliable, mild, catalyst-free, and inexpensive. Ultrasonic irradiation on the reaction mixture leads to fine emulsion between the reactants and violent collapses of a lot of cavitation bubbles in less than a microsecond releases extreme heat, leading to cross the activation energy barrier. In the absence of ultrasonic irradiation, a trace amount of the product was formed after 50 min. The superiority of the ultrasound irradiation over other methods in the synthesis of dibenzo [b,f][1,4] oxazepine derivatives is its low reaction temperature and operational simplicity in approximately same yields.
Authors and Affiliations
Hamide Saeidian, Hossein Paghandeh, Ebrahim Saeedian Moghadam, Zohreh Mirjafary, Mohammad Ghaffarzadeh
Keywords
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- EP ID EP252771
- DOI 10.22631/ajgc.2017.95751.1018
- Views 105
- Downloads 0
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