PEROKSIDAZE KATALIZUOJAMOS BISFENOLIO A OKSIDACIJOS REAKCIJOS, DALYVAUJANT FENOKSAZINO DARINIUI, TYRIMAS
Journal Title: Jaunųjų mokslininkų darbai - Year 2017, Vol 47, Issue 2
Abstract
Bisfenolis A (Bis A) yra itin kenksmingas žmonių sveikatai, todėl ieškoma būdų, kaip jį neutralizuoti. Rekombinantinė Coprinus cinereus peroksidazė (rCiP) bisfenolį A oksiduoja lėtai, tačiau pridėjus 3-(10H-fenoksazin-10-il) propioninės rūgšties (PPA) reakcijos greitis išauga. Nustatytos Bis A pradinio oksidacijos reakcijos greičio priklausomybės nuo fermento, substrato, mediatoriaus koncentracijų, išsiaiškinta, kokia yra PPA pradinio oksidacijos reakcijos greičio priklausomybė nuo mediatoriaus koncentracijos. Vykstantiems procesams aprašyti pasiūlyta kinetinė schema. Iš tiesiogiai gautų duomenų ir modeliuojant apskaičiuoti kinetiniai parametrai.
Authors and Affiliations
Rūta Ivanec Goranona, Pranas Zazerskis
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