Synthesis and thermodynamics of the reactions of [Pd(Eten)(H2O)2]2+ with ligands of biological significane with reference to the antitumour activity

Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2015, Vol 11, Issue 1

Abstract

Pd(Eten)Cl2  complex, where Eten = N-ethylethylenediamine , was synthesized and characterized by elemental analysis and spectroscopic techniques. The stoichiometry and stability of the complexes formed between [Pd(Eten)(H2O)2]2+ and various biologically relevant ligands  as adenine, adenosine, adenosine-5’-monophosphate  and some selected peptides  were investigated at 25ºC and 0.1 M ionic strength. The speciation diagrams of the complexes formed in solutions are evaluated. Thermodynamic parameters for Pd(Eten)-glycylglycine complexes were estimated.

Authors and Affiliations

Fawzia Al-Kallaf, Perihan A. Khalf-Allaa, Abeer Al-Bassam, Mohamed M. Shoukry

Keywords

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  • EP ID EP652817
  • DOI 10.24297/jac.v11i1.2222
  • Views 131
  • Downloads 0

How To Cite

Fawzia Al-Kallaf, Perihan A. Khalf-Allaa, Abeer Al-Bassam, Mohamed M. Shoukry (2015). Synthesis and thermodynamics of the reactions of [Pd(Eten)(H2O)2]2+ with ligands of biological significane with reference to the antitumour activity. JOURNAL OF ADVANCES IN CHEMISTRY, 11(1), 3324-3334. https://europub.co.uk/articles/-A-652817