Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole

Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 7, Issue 3

Abstract

N-(α-amino-alkyl)-benzotriazole, a derivative of Benzotriazole (BTZ), was synthesized via a Mannich reaction addition. The chemical characterization shows that when C19H32N4supramolecule is subjected to heating process the covalent bonds of aminal carbon are broken, modifying supramolecule structure, this results in a rearrangement to the structure dodecan ammonium-1-benzotriazol-1-ate, [BTZ- amine12+].Quantum chemical calculations based on DFT method were performed on the C19H32N4 molecule. The results show that in a derivative of BTZ exists a weak bond where its break may occur.

Authors and Affiliations

Araceli Vega-Paz, Luisa E. Montiel, Carolina Zuriaga-Monroy, José-Manuel Martínez-Magadán, Jesús Marín-Cruz

Keywords

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  • EP ID EP652674
  • DOI 10.24297/jac.v7i3.2387
  • Views 161
  • Downloads 0

How To Cite

Araceli Vega-Paz, Luisa E. Montiel, Carolina Zuriaga-Monroy, José-Manuel Martínez-Magadán, Jesús Marín-Cruz (2014). Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole. JOURNAL OF ADVANCES IN CHEMISTRY, 7(3), 1440-1447. https://europub.co.uk/articles/-A-652674