Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 7, Issue 3
Abstract
N-(α-amino-alkyl)-benzotriazole, a derivative of Benzotriazole (BTZ), was synthesized via a Mannich reaction addition. The chemical characterization shows that when C19H32N4supramolecule is subjected to heating process the covalent bonds of aminal carbon are broken, modifying supramolecule structure, this results in a rearrangement to the structure dodecan ammonium-1-benzotriazol-1-ate, [BTZ- amine12+].Quantum chemical calculations based on DFT method were performed on the C19H32N4 molecule. The results show that in a derivative of BTZ exists a weak bond where its break may occur.
Authors and Affiliations
Araceli Vega-Paz, Luisa E. Montiel, Carolina Zuriaga-Monroy, José-Manuel Martínez-Magadán, Jesús Marín-Cruz
Keywords
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- EP ID EP652674
- DOI 10.24297/jac.v7i3.2387
- Views 155
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