Embedding neat and carboxylated nanodiamonds into polypropylene membranes to enhance antifouling properties
Journal Title: Polyolefins Journal - Year 2019, Vol 6, Issue 1
Abstract
The aim of the present work is to enhance the antifouling properties of polypropylene (PP) membrane based on hydrophilicity improvement. Different contents of neat and modifed nanodiamond (0.25, 0.50, 0.75 and 1.00 wt.%) were embedded into PP membranes. Nanodiamond nanoparticles were carboxylated by heat treatment method and the presence of carboxyl functional groups on the surface of nanoparticles was confrmed by FTIR analysis. Membranes were then characterized by FESEM, contact angle and tensile strength tests. At the same content of nanoparticles, hydrophilicity, pure water flux and tensile strength of PP/ND-COOH membranes were more than those of PP/ND membranes. Membranes embedded with 0.75 wt. % of neat and modifed nanoparticles were used in a submerged membrane bioreactor (SMBR) system along with neat PP membrane. The results showed that critical flux values for neat PP, PP/ND and PP/ND-COOH membranes were 7, 18 and 22 L/(m2.h), respectively. Analysis of fouling mechanisms revealed that antifouling properties of 0.75 wt. % PP/ND-COOH membrane were higher than those of other two ones so that irreversible fouling ratio decreased from 88.9% for neat PP to 47.8% for PP/ND-COOH membrane.
Authors and Affiliations
Shahab Hoseinpour, Yoones Jafarzadeh, Reza Yegani, Sepideh Masoumi
Keywords
Related Articles
- EP ID EP438530
- DOI 10.22063/poj.2018.2264.1120
- Views 127
- Downloads 0
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