Preparation of high performance PP/ reduced graphene oxide nanocomposites through a combined in situ polymerization and masterbatch method
Journal Title: Polyolefins Journal - Year 2017, Vol 4, Issue 1
Abstract
Despite the great potential of graphene as a nanofiller, achieving homogeneous dispersion remains the key challenge for effectively reinforcing polyolefin (such as polyethylene (PE) and polypropylene (PP)) nanocomposites. Therefore, in this research, we report a facile combined in situ polymerization and masterbatch method for fabricating PP/reduced graphene oxide (rGO) nanocomposites. In the polymerization stage, the synthesized catalyst exhibited a very high activity toward propylene polymerization, while the resultant PP/rGO with a very high isotactic index (I.I. = 99.3), broad molecular weight distribution (Mw/Mn = 14.9), and thermal stability was produced. After meltblending with commercial PP, a significantly increased modulus along with no observable change in tensile strength and elongation-at-break were achieved via the addition of a very small amount of rGO; these properties resulted from the suitable dispersion and good interface adhesion of the graphene sheet and PP matrix. Thus, this work provides a method for production of high performance PP.
Authors and Affiliations
He-Xin Zhang, Seung-Ri Lee, Dong-Ho Lee, Xue-Quan Zhang, Keun-Byoung Yoon
Keywords
Related Articles
- EP ID EP283185
- DOI 10.22063/POJ.2016.1375
- Views 118
- Downloads 0
Synthesis of cyclic olefin polymers with high glass transition temperature and high transparency using tungsten-based catalyst system
Novel cyclic olefin polymers (COPs) derived from bulky cyclic olefins, tricyclodipentadiene (TCPD) and tricyclo[6.4.0.19,12]-tridec-10-ene (TTE), with high glass transition temperature (Tg), excellent thermal stability,...
Evaluation of continuous and discrete melting endotherms in determination of structural heterogeneities in Ziegler-Natta catalyzed linear low density polyethylene
Ethylene / 1-butene copolymers at different comonomer levels were synthesized using Ziegler-Natta catalyst to evaluate the applicability of thermal fractionation methods in predicting chemical composition distribution (C...
Discovery and development of metallocene-based polyolefins with special properties
Beside Ziegler-Natta and Phillips catalysts the development of methylaluminoxane (MAO) as cocatalyst in combination with metallocenes or other transition metal complexes for the polymerization of olefins has widely incre...
Effects of FeCl3 doping on the performance of MgCl2/TiCl4/DNPB catalyst in 1-hexene polymerization
The aim of this study was to examine the effect of catalyst doping on the performance of MgCl2. EtOH/TiCl4 catalyst system. In this regard, a series of undoped as well as FeCl3-doped catalysts was prepared and employed i...
Study of Ziegler-Natta/(2-PhInd)2ZrCl2 hybrid catalysts performance in slurry propylene polymerization
Several types of hybrid catalysts are made through mixing of 4th generation Ziegler-Natta (ZN) and (2-PhInd)2ZrCl2 metallocene catalysts using triethylaluminum (TEA) as coupling agent. Response surface methodology (RSM)...